Synthesis, characterization and enhanced visible-light photocatalytic activity of Zn2SnO4/C nanocomposites with truncated octahedron morphology

Abstract

Novel Zn2SnO4/C nanocomposites with truncated octahedron morphology were constructed using a two-step hydrothermal synthesis route combined with subsequent calcination. The as-prepared samples were characterized by X–ray diffraction (XRD), Fourier transform infrared spectroscopy (FT–IR), Raman spectroscopy, field–emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), UV–vis diffuse reflection spectroscopy, photoluminescence spectroscopy (PL), and Brunauer–Emmett–Teller surface area measurements. The result of FESEM showed that the as-prepared Zn2SnO4/C nanocomposites are composed of numerous uniform nanoparticles with regular truncated octahedron morphology. Raman spectral characterization combined with HRTEM result revealed that a thin layer of carbon was attached on the surface of Zn2SnO4. Using rhodamine B (RhB) as a model organic pollutant, the visible-light photocatalytic activities of the as-prepared samples were investigated, and the photocatalytic mechanism was discussed. Compared with pure Zn2SnO4, Zn2SnO4/C nanocomposites exhibited much better visible-light photocatalytic activity. The increase in the photocatalytic activity of Zn2SnO4/C nanocomposites was mainly attributed to the enhancement of the optical absorption capability and efficient separation of photogenerated electron-hole pairs.