Abstract

Synthesis, structural characterization and redox properties of three heterobimetallic complexes with formule {[NiCu(Ln)(CH3OH)3]·CH3OH} using [Cu(H2Ln)(H2O)] as metalloligand have been demonstrated in the present paper. Electronic spectroscopy suggests that the copper center has a pseudo square pyramidal stereochemistry in all the complexes while the nickel center has a distorted octahedral stereochemistry. The electron transfer reactions of the complexes have been investigated by cyclic voltammetry.

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