Abstract
A new dinuclear vanadium(IV) complex [(VO)2(μ-HBPA)2(μ-SO4)].4.75H2O was synthesized by the reaction between a bipodal N2O-donor ligand N-(2-hydroxybenzyl)-N-(pyridin-2-ylmethyl)amine (HBPA) and vanadyl sulfate. The complex was characterized by elemental analysis, thermogravimetric, electrochemical analysis, ESI-MS, FT-IR and UV–visible. The structure was determined by single crystal X-ray diffraction. The two non-equivalent vanadium(IV) ions are hexacoordinated being bridge-coordinated by the oxygen atoms from of HBPA and sulfate group. The complex was studied by DFT calculations and showed high polarity.
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