Abstract

Abstract A square-planar platinate(II) complex, [Pt(d-pen-N,S)2]2− (d-H2pen: d-penicillamine), was newly synthesized by the 1:2 reaction of [PtCl4]2− with d-pen in water under severe conditions (reflux for 12 h). This complex formed both cis and trans isomers, which were separated, isolated, and crystallographically characterized.

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