Abstract
Reaction of the symmetrical α-diimine ligand L with either PtCl 2 or PdCl 2(C 6H 5CN) 2 affords the square planar d 8 complexes 1 and 2, respectively. Both complexes were characterized by NMR spectroscopy and elemental analysis. The solid-state structure of 1, which crystallized in the triclinic space group P 1 ̄ with unit cell parameters a=8.688(2) A ̊ , b=13.840(2) A ̊ , c=14.136(2) A ̊ , α=111.346(14)°, β=103.82(2)°, and γ=102.69(2)°, was established by X-ray crystallography.
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