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Abstract
A novel three-dimensional supramolecular compound formed by Mn(II) and pyridine-2,5-dicarboxylic acid of formula [Mn(Pydc)2(H2O)2] (Pydc = pyridine-2,5-dicarboxylic acid) has been synthesized and characterized by elemental analyses, IR, electronic spectra, thermogravimetric analysis and X-ray diffraction techniques. The X-ray structure shows that the central Mn(II) ion is coordinated by two water molecules and two chelated Pydc ligands. Water molecules coordinate with Mn(II) ions in the cis mode. Intermolecular hydrogen bonds play an important role in stabilization of the lattice and construction of the supramolecular network.
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