Abstract
A nitrate salt of bis[4-bromo-2-(pyridin-2-ylmethyliminomethyl)phenolato]iron(III), [Fe(C13H10BrN2O)2].NO3, has been obtained and characterized by elemental analysis and X-ray single crystal determination. The complex crystallizes in the tetragonal space group P42/n with unit cell dimensions a = b = 17.608(3) A, c = 17.199(3) A, V = 5332.4(15) A3, Z = 8, R 1 = 0.0444 and wR2 = 0.0902. The complex consists of a [Fe(C13H10BrN2O)2]+ cation and a nitrate anion. The Fe atom in the cation is six-coordinated in an octahedral geometry. In the crystal structure, molecules are linked through weak C–H⋯O intermolecular hydrogen bonds, forming chains running along the c axis.
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