Synthesis, characterization, and CO sensing properties of NiO thin film for commercial aircraft applications

Abstract

Abstract The detection of combustion gases such as carbon monoxide (CO) and fuel leaks is a concern in regard to aeronautical safety and has led to the development of semiconductor sensors. The focus of this work is the detection of CO within commercial aircraft using a thin film of nickel oxide (NiO) as the sensing element. The NiO phase was synthesized using the sol-gel method using a modification of the procedures proposed by N. Talebian and B. Pejova. Microstructural characterization of the NiO thin film was performed using scanning electron microscopy (SEM), X-ray diffraction (XRD), and transmission electron microscopy (TEM). Optical analysis was carried out using diffuse reflectance (UV-VIS) spectroscopy. The results showed that the NiO thin film was homogeneous and composed of nodular nanoparticles with size between 10 and 15 nm and thickness of 75 nm. The band gap value was 3.3 eV, which is consistent with p-type semiconductors. The sensitivity of the devices was determined by means of the static environment method. The best operation temperature was 200°C for the device with 100-µm spacing between tracks, which gave a response time of 165 seconds and recovery time of 212 seconds according the results of a flow-through method. The device with this track spacing is ideal for CO detection at 50 ppm, at which the first symptoms of intoxication appear in humans inside commercial aircraft.