Synthesis, characterization and application of a magnetic nanoencapsulated PCM in enhancing the natural convection in a cube cavity

Abstract

Encapsulation of phase change materials (PCMs) is an intelligently effective way to overcome the challenges of PCMs usage in heat storage and transfer applications. At the first stage of the current study, a novel magnetic nanoencapsulated PCM (M−NEnPCM) consisting of n-Octadecane (n-C18) coated with a poly methyl methacrylate (PMMA) shell was synthesized through the miniemulsion ultrasonic-assistant polymerization technique. The magnetic property was introduced to the nanocapsules by adding surface-modified Fe3O4 nanoparticles into the core during the formation step. The dynamic light scattering (DLS) results showed an average nanocapsule size of 78 nm. The scanning electron microscope (SEM) along with transmission electron microscope (TEM) images confirmed the spherical shape with a core/shell structure of the M−NEnPCM. According to the differential scanning calorimetry (DSC), M−NEnPCM had melting and crystallization latent heats of 116.47 and 124.71 J/g, respectively. Moreover, based on vibrating sample magnetometry (VSM) results, the superparamagnetic property of M−NEnPCM is proved. At the second stage, the performance of water suspensions containing different amounts of the as-prepared nanocapsules in enhancing the natural convection in a cube cavity was investigated under various heat fluxes and magnetic field flux densities. The results illustrated that the use of nanocapsules leads to enhance the natural convection up to 2 times higher than that of pure water; while there are optimum levels of M−NEnPCM concentration and magnetic field flux density at which the heat transfer coefficient is maximized.