Abstract
A series of alkynylrhenium(I) tricarbonyl diimine complexes has been synthesized and characterized. A blue shift of the intense low-energy MLCT absorption band in the visible region was observed upon coordination of Cu(I) or Ag(I). This class of complexes has been found to show rich thermotropic gelation behaviour upon Cu(I) or Ag(I) coordination with their morphology characterized by SEM. Their variable-temperature UV/Vis absorption and emission properties have also been studied. A blue shift in the MLCT absorption band and the switching on of luminescence were observed upon sol-gel transition.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
