Abstract
A new series of mesogenic aroylhydrazone-based ligands, N-[4-(4′-alkoxy)benzoyloxybenzylidene]-N′-[4″-alkoxybenzoyl]hydrazine with either the same or different peripheral alkyl chains, and nickel(II) complexes of some of them have been synthesised. They were characterised by elemental analyses, Fourier transform infrared, proton and carbon nuclear magnetic resonance and ultraviolet-visible spectroscopy. The mesomorphic properties of these compounds were investigated by differential scanning calorimetry and polarising optical microscopy. All the aroylhydrazones, except those with no lateral chains on either end of the molecule and where m = n = 14, 16, exhibit a monotropic or enantiotropic smectic C mesophase, which are almost insensitive to the peripheral alkoxy chain length. The square planar nickel(II) complexes of the ligands show only an isotropic phase at higher temperature (>175°C) and no mesogenic nature is observed. Density functional theory calculations have been performed using the GAUSSIAN-03 program at the Becke, three-parameter, Lee–Yang–Parr level to obtain the stable electronic structure of the ligand.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have