Abstract
An isostructural series of nickel, palladium and platinum halido complexes of the type [(POCOP)MX] [POCOP = κ3‐C5H3‐2,6‐(OPtBu2)2; X = F, Cl, I] was prepared and fully characterised. Molecular structures of complexes 1‐I, 2‐I, 3‐Cl and 3‐I are reported and show the typical distorted square‐planar coordination geometries. In the presence of HF, Ni and Pt fluorido complexes 1‐F and 3‐F show pronounced hydrogen bonding to HF to form bifluorido complexes 1‐FHF and 3‐FHF, respectively, which were characterised by X‐ray analysis. In the solid state, all complexes are isomorphous and crystallise in the triclinic space group P1.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.