Abstract
The title compound, Cu 8(μ-I)(μ 6-S)(DTP) 6 (DTP=diethyldithiophosphate), has been synthesized by the reaction of Mo 3(μ 3-S)(μ-O)(μ-S) 2(DTP) 4(CH 3CN) with CuI, and its structure has been determined by X-ray crystallography. Crystal data: C 24H 60Cu 8IO 12P 6S 13, Mr=1778.54, trigonal, R-3, Z=3, a=20.734(3), c=11.874(2) Å, V=4420.7(13) A ̊ 3 , D c =2.004 g cm −3 . An interstitial μ 6-S is established in the Cu 8 cubic center. The octanuclear cubes are linked together by μ-I so that a strict infinite linear polymeric cluster chain is formed along the [0 0 1] direction.
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