Abstract
The title compound, C 7 H 7 N 3 S, (2-Hydrazinyl-1,3-benzothiophene) was prepared from the reaction of 2-amino-benzothiazole treated with hydrazine hydrate. It crystallizes in the monoclinic space group P2 1 /n with unit cell parameters a = 10.839(5), b = 5.752(5), c = 12.961(5) A, β = 110.005(5)o, Z = 4. The crystal structure is stabilized by N-H…N [N2-H5...N3, N1-H12...N1] intermolecular interactons, N2-H5...N3 interaction is responsible for the formation of dimers corresponding to R 2 2 (8) graph-set motif and the dimers are further connected by N1-H12…N1 hydrogen bonding forming dimeric chains. Besides this, there is N1-H11… ᴨ interaction which is responsible for the stabilization of the crystal structure. The packing diagram of the title compound represents the dimeric chains extending along the b-axi
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