Abstract
New Hofmann type clathrates in the form of M(pp) 2Ni(CN) 4·2G (where pp = 1-phenylpiperazine, G = 1,4-dioxane and M = Ni, Co or Cd) have been prepared in powder form and their FT-IR and FT-Raman spectra are reported. The results suggest that the present compounds are similar in structure to the Hofmann type clathrates and their structures consist of conjugated polymeric layers of |M–Ni(CN) 4| ∞ with the pp bound to the metal (M) atom.
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Schedule a callMore From: Spectrochimica Acta Part A: Molecular Spectroscopy
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