Abstract
The neutral-component complexes (HCOOH)3•(18-crown-6)2, (CH3COOH)2•18-crown-6, and various halogenated CH3COOH/18-crown-6 adducts have been isolated and studied by infrared and Raman spectroscopy. The halogenated (F, Cl, and Br) derivatives, which occur as (acid•water)x•18-crown-6(x = 1 or 2) adducts, probably have a structure which is similar to that of the known CH2(CN)COOH•H2O•18-crown-6 complex.
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