Abstract
Cyclometallation of olefins with AlEt3 in the presence of Cp2ZrCl2 affording five-membered monosubstituted cyclic organoaluminum compounds, was studied by the semiempirical quantum-chemical PM3 method. The proposed model of catalytic cycloalumination of styrene catalyzed by Cp2ZrCl2 is in a good accordance with experimental data obtained by dynamic NMR spectroscopy.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR, Division of chemical science
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