Abstract
Enantiomerically pure open chain α-pyrrylalditols 2, 3, 5 and 7 and dinuclear dipyrrylmethanes 8–10 bearing chiral alditolyl bridges have been synthesized by direct coupling of glyceraldehyde 1, arabinose 4, and glucose 6 with pyrrole metal reagents based on magnesium-titanium IV or magnesium-cerium III blends. The mononuclear and dinuclear compounds were then exploited as precursors for the preparation of either cyclic C-nucleoside analogs 11–14, or the sugar porphyrin 16.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
