Abstract
N-Arylsulfonyl carbonimidodithioic acid dimethyl ester has been reacted with nitroalkanes to generate the corresponding 1-alkylthio-1-aryl sulfonamido-2-nitroethylenes; the latter have been hydrolysed to N-arylsulfonyl-2-nitro-acetamides. Solvent dependent imine-enamine tautomerism is observed in the nitroenamines 2a-d.
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