Abstract

We report in this paper the growth of PbS shells over colloidal PbSe nanocrystal quantumdots (NQDs) with monolayer-precision. The technique of successive ion layeradsorption and reaction (SILAR) has been adapted to the growth of high-qualitycore–shell nanocrystals. The core–shell infrared NQDs were ligand-exchanged withshort-chain octylamine, and the photoluminescence efficiency of the surface-engineeredcore–shell nanoparticles was substantially higher than that of the plain core structuresundergoing the same surface processing, which reveals less ligand dependence andenhanced chemical robustness in the core–shell NQDs. The reported results openup the possibility of incorporating semiconductor infrared NQDs in the siliconmatrix to develop all-inorganic light-emitting heterojunctions on silicon substrates.

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