Abstract
Methods of synthesis of ruthenium tetra-tert-butylphthalocyaninate (PctRu) were developed. The synthesis performed in both autoclave and in open system (in isoamyl alcohol in the presence (1,8-diazabicyclo[5,4,0]undecene) resulted in PctRu(СО) containing CO as axial ligand. When quinoline was used in the synthesis of PctRu, the PctRu(Iqnl)2 complex was obtained with two isoquinoline molecules (Iqnl) as axial ligands, which were detached consecutively in the course of thermogravimetric analysis. The compounds formed were studied by different physicochemical methods: electron, IR, and 1H NMR spectroscopies, MALDI-TOF mass spectroscopy, thermogravimetric and elemental analyses.
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