Abstract
AbstractThe antimony analogue of choline bromide, [Me3SbCH2CH2OH]Br (1), is formed by the reaction of Me3Sb with BrCH2CH2OH. Crystals of (Me3SbCH2COO)8(NaBr)7(MeOH)9(H2O) (2) are obtained from [Me3SbCH2COOH]Br and Na2CO3 in methanol. Crystals of 1 contain stibonium cations with intramolecular coordination of the ethanolic group. The structure of 2 features supramolecular units where the carboxylic groups of stiba betaine molecules are in bridging positions between sodium ions. Copyright © 2005 John Wiley & Sons, Ltd.
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