Abstract

An indium phosphate, [In4(4,4‘-bipy)3(HPO4)4(H2PO4)4]·4H2O, prepared as single crystals under solvothermal conditions, has a new structure which consists of neutral sheets of indium phosphate linked through 4,4‘-bipyridine pillars to generate channels in which water molecules reside. The structure of the anhydrous compound, In4(4,4‘-bipy)3(HPO4)4(H2PO4)4, is also determined.

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