Abstract
A method for the synthesis of the silver(I) complex with the closo-decaborate anion and triphenylphosphine [Ag2(Ph3P)2B10H10]n was developed and the structure of this complex was studied. The polymeric chain of the complex is formed with participation of Ag(I) atoms, which coordinate the B10H102− anions through the apical (B(1)–B(2), B(9)–B(10)) and equatorial (B(3)–B(6), B(5)–B(8)) edges, the metalligand bonding occurring through three-center two-electron bonds (MHB). The P atoms of two triphenylphosphine molecules are also incorporated in the inner coordination sphere of the metal: the CN of the silver atom is 4 + 1.
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