Abstract
One of the products of the reaction between Re3S7Br7 and PPh3 has been isolated in crystalline state and characterized by single crystal X-ray diffraction (XRD), mass-spectrometry, and EPR spectroscopy. The crystalline phase obtained is a co-crystallization product of two cluster complexes: [Re3(μ3-S)2(μ-S)2(μ-Br)Br3(PPh3)3] (1a) an [Re3(μ3-S)2(μ-S)(μ-Br)2Br3(PPh3)3] (1b). The ratio 1a:1b in the investigated single crystal sample is ∼7:3.
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