Abstract
The reaction of tetraorganylphosphonium and tetraethylammonium chlorides with hexachloroplatinic acid hydrate in a mixture of acetonitrile and diethyl sulfoxide produced [Ph3PEt][PtCl5(deso-S)] and [Et4N][PtCl5(deso-S)] complexes containing tetrahedral tetraorganylphosphonium or tetraethylammonium cations and octahedral diethylsulfoxidopentachloroplatinate anions.
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