Abstract
Reactions of Ph 3SnCl, PhSnCl 3 and Ph 3SnSnPh 3 with ytterbium in THF lead to the formation of the complex (Ph 3Sn 2Yb(THF) 4 ( 1 * in high yields. According to X-ray data, tin atoms in complex 1 are covalently bonded with the ytterbium atom. Ionic organotin complex of ytterbium [(Ph 3Sn 3Sn] − 2[Yb 2Cl 2(DME) 6] 2+ ( 2 was synthesised in 75% yield by the reaction of Ph 2SnCl 2 with ytterbium. According to X-ray analysis, the compound consists of [(Ph 3Sn 3Sn] − anions and dimeric ytterbium cations with μ 2-bridged chlorine atoms [(DME) 3YbClYb(DME 3] 2+.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
