Abstract
The compound (NH4)3[UO2(CH3COO)3]2(NCS) (I) was synthesized and examined by single crystal X-ray diffraction analysis. The compound crystallizes in the rhombic system with the unit cell parameters a = 11.5546(4), b = 18.5548(7), c = 6.7222(3) A, V = 1441.19(10) A3, space group P21212, Z = 2, R = 0.0345. The uranium-containing structural units of crystals of I are isolated mononuclear groups [UO2(CH3COO)3]− belonging to crystal-chemical group AB 3 01 (A = UO 2 2+ , B01 = CH3COO−) of uranyl complexes. The specific features of packing of the uranium-containing complexes in the crystal structure are considered.
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