Abstract
New Np(V) selenate complexes with various outer-sphere cations, K[(NpO2)(SeO4)(H2O)] (1), Rb[(NpO2)(SeO4)(H2O)] (2), and Cs[(NpO2)(SeO4)(H2O)] (3), were synthesized and studied by single-crystal X-ray diffraction. The compounds are isostructural; the Np(V) coordination polyhedron is a pentagonal bipyramid. Neptunyl(V) ions NpO2+ are combined in zigzag chains by cation-cation interaction.
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