Synthesis and structure of mixed-metal thiolate complex Cp′Cr(CO) 2(μ-SBu)Pt(PPh 3) 2: Side-on-coordination of Cr–S double bond with platinum

Abstract

The reaction of [Cp′Cr(CO) 2(μ-SBu)] 2 ( 1) (Cp′ = MeC 5H 4) with (PPh 3) 2Pt(PhC CPh) gives Cp′Cr(CO) 2(μ-SBu)Pt(PPh 3) 2 ( 2) which could be regarded as a product of the substitution of acetylene ligand at platinum by a monomeric chromium–thiolate fragment. According to the X-ray diffraction analysis 2 contains single Cr–Pt (2.7538(15)) and Pt–S (2.294(2) Å) bonds while Cr–S bond (2.274(3) Å) is shortened in comparison with ordinary Cr–S bonds (2.4107(4)–2.4311(4) Å) in 1. The bonding between Cr–S fragment and platinum atom is similar to the olefine coordination in their platinum complexes.