Abstract
Trinuclear [M3S4(OCH3)3](edpp)3]+ complexes, 1+ (M = Mo) and 2+ (M = W) bearing (2-aminoethyl)diphenylphosphine (edpp), have been isolated and fully characterized. Molybdenum and tungsten halide precursors react with methanol in the presence of Et3N, to yield the respective methoxo-terminated clusters. The crystal structures of complexes 1+ and 2+ confirm that methoxo ligands are coordinated to the metal centers. Gas-phase dissociation of the novel methoxo cluster cations using ESI tandem mass spectrometry reveals the sequential elimination of three neutral methanol molecules under collision induced dissociation (CID) conditions to form metal/imino M = NH cluster species.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
