Abstract

Crystal hydrates were synthesized based on aquaions of noble metals [M(H2O)6]F3·nH2O, where n = 3–8 and M = Ir, Rh. The structure of the resulting crystal hydrates with three aqueous molecules is characterized by the space group P3, Z = 1 and has a layered form. The positively charged layers [M(H2O)6F2+ which alter with negatively charged layers of the composition ∼-·3H2O, are located perpendicular to the c axis. According to X-ray structural and nuclear magnetic resonance data, the water molecules and the F- ions in the negatively charged layers are disordered.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.