Abstract
The reactions of tetraorganylphosphonium and trimethylammonium chlorides with hexachloroplatinic acid hydrate in an acetonitrile–diethyl sulfoxide solution produced [Ph3PCH=CHCH3]2[PtCl6], [Ph3PCH2OCH3]2[PtCl6], and [Me3NH]2[PtCl6] complexes. The structure of the resultant platinum complexes was examined by X-ray diffraction analysis.
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