Abstract
AbstractReaction of Fc(S)PS2P(S)Fc with NaOEt gives the non symmetric phosphonodithioato anion [Fc(EtO)PS2]‐ which can be complexed to a range of metal ions. The group 10 metals (Ni, Pd and Pt) adopt [ML2] complexes with square planar coordination. The first known mercury phosphonodithioate complex is shown to adopt a unique dimeric [M2L4] structure. A new structural motif for lead phosphonodithioate complexes is reported consisting of [PbL2] units joined by Pb···S interactions to form distinct dimeric pairs. All new compounds have been characterized spectroscopically and four demonstrative X‐ray structures are reported.
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