Abstract
AbstractA one‐dimensional aluminum phosphate, [NH3(CH2)2NH2(CH2)3NH3]3+ [Al(PO4)2]3—, has been synthesized hydrothermally in the presence of N‐(2‐Aminoethyl‐)1, 3‐diaminopropane (AEDAP) and its structure determined by single crystal X‐ray diffraction. Crystal data: space group = Pbca (no. 61), a = 16.850(2), b = 8.832(1), c = 17.688(4)Å, V = 2632.4(2)Å3, Z = 8, R1 = 0.0389 [5663 observed reflections with I > 2σ(I)]. The structure consists of anionic [Al(PO4)2]3— chains built up from AlO4 and PO4 tetrahedra, in which all the AlO4 vertices are shared and each PO4 tetrahedron possesses two terminal P=O linkages. The cations, which balances the negative charge of the chains, are located in between the chains and interact with the oxygen atoms through strong N—H···O hydrogen bonds. Additional characterization of the compound by powder XRD and MAS‐NMR has also been performed and described.
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