Abstract
A new tin(II) phosphate, [NH3CH2CH(NH3)CH3]0.5[Sn4P3O12]·H2O, was synthesized by hydrothermal technique. It crystallizes in monoclinic space group P21/c (No. 14) with lattice parameters a=7.326(1) Å, b=23.614(3) Å, c=9.081(1) Å, β=102.8(1)°, V=1532.1(1) Å3, Z=3, R=4.3%. The structure consists of one-dimensional channels, constituting a network of strictly alternating SnO3 and PO4 moieties connected through vertices. The structure-directing amine molecule 1,2-diaminopropane occupies the channels along with water molecules.
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