Abstract
AbstractThe structures of the hitherto unknown bis(double helicate) 10 and its cryptatoclathrate (10)2·2THF were unequivocally determined by X‐ray diffraction. Bis(double helicate) 10 is formed in a one‐pot synthesis starting from CH‐acidic bis (tetrazolylmethyl ketone) 9 and Zn(OAc)2. The formation of racemic, homochiral 10 from [Zn2L32] fragments, which are formed in a self‐assembly process, is governed by chiral self‐recognition. According to NMR studies only 10 is present in solution. 13C CP/MAS NMR spectroscopy and X‐ray analysis confirm aggregation of 10 with two molecules of THF to yield the inclusion compound (10)2·2 THF in the solid state.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
