Abstract
AbstractSingle crystals of new Mn2[Bi2O](SeO3)4(I), MnBi(SeO3)2Cl (II), MnIIMnIII(SeO3)2Cl (III), Mn5(SeO3)2Cl6(IV), and Mn4(Mn5,Bi)(SeO3)8Cl5(V) have been synthesized by chemical vapour transport and hydrothermal methods. They have been structurally characterized by single crystal X-ray diffraction analysis. The compoundsII–Vare the first Mn selenite chlorides, while theI,IIandVcompounds are the first Bi-containing Mn oxoselenites. Structural relationships of the new phases with other compounds are discussed. An overview of the mixed-ligand MnOmClnpolyhedra in inorganic compounds is given.
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Schedule a callMore From: Zeitschrift für Kristallographie - Crystalline Materials
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