Abstract

Complexes of the general formula, Me2SiL2 (where, LH = semi- and thiosemicarbazones) have been prepared by reacting dimethylsilicondichloride with the ligand in a 1 : 2 (metalloid : ligand) molar ratio. These complexes have been characterized by elemental analysis, molecular weight determinations and conductivity measurements, and structures have been proposed using electronic, IR, 1H NMR and 13C NMR spectral studies. The data suggest that the ligands function as monobasic bidentate towards the metalloid atom.

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