Synthesis and structural characterization of tris(2-mercapto-1-methylbenzimidazolyl)hydroborato cadmium halide complexes, {[Tm(MeBenz)]Cd(μ-Cl)}2 and [Tm(MeBenz)]CdI: a rare example of cadmium in a trigonal bipyramidal sulfur-rich coordination environment.

Abstract

The tris(2-mercapto-1-methylbenzimidazolyl)hydroborato cadmium complexes, {[Tm(MeBenz)]Cd(μ-Cl)}2 and [Tm(MeBenz)]CdI, have been synthesized via the reactions of [Tm(MeBenz)]K with CdCl2 and CdI2, respectively. While X-ray diffraction studies demonstrate that the iodide derivative, [Tm(MeBenz)]CdI, is a monomer, the chloride derivative, {[Tm(MeBenz)]Cd(μ-Cl)}2, exists as a dimer, which is unprecedented for Group 12 [Tm(R)]MX (X = Cl, Br, I) compounds. Furthermore, the cadmium centers of {[Tm(MeBenz)]Cd(μ-Cl)}2 are trigonal bipyramidal, which is an uncommon motif for cadmium complexes with a [S3Cl2] coordination sphere.