Abstract

AbstractThe neutral pentacoordinate silicon(IV) complex 10 (SiON3C skeleton) and the neutral hexacoordinate silicon(IV) complex 11 (SiON4C skeleton) were synthesized, starting from methyldi(thiocyanato‐N)silane (7). In addition to their monodentate thiocyanato‐N and methyl ligands, these compounds contain a tridentate dianionic O,N,N ligand (10) or a tridentate monoanionic O,N,N ligand (11). Compounds 10 and 11 were characterized by single‐crystal X‐ray diffraction and solid‐state and solution NMR spectroscopy. According to these studies, compounds 10 and 11 exist in solution as well.

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