Abstract
A series of 18-membered mixed nitrogen, oxygen and sulphur donor atom-containing macrocyclic complexes [ML 2]X 2-[ML 2]X 2 (M = Co 11, Ni 11 and Cu 11; X = Cl, Br or NO 3) have been synthesized by the template condensation reaction of 2,5-diformylfuran, β-mercaptoethylamine or o-aminothiophenol and 1,3-dibromopropane in ethanol medium and have been characterized through IR, 1H NMR, EPR and electronic spectral studies, conductivity and magnetic susceptibility measurements. An octahedral geometry has been suggested for the cobalt complexes while square planar and five-coordinate square pyramidal geometry is proposed for the nickel and copper complexes, respectively.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
