Abstract
AbstractTwo novel metal complexes derived from interactions of Cd2+ and Hg2+ ions with 3‐aminoquinoline in the molar ratio 1 : 2 are reported. The synthesized and isolated metal complexes were characterized by UV/VIS, FT‐IR, 1H‐ and 13C‐NMR, and ESI‐MS spectroscopic studies, and elemental analyses. FT‐IR and NMR studies confirmed that the NH2 group remains uncoordinated in both synthesized complexes. The molecular structure of the CdII complex was additionally determined by X‐ray single‐crystal analysis. The Cd complex crystallizes in the triclinic centrosymmetric P$\bar 1$ space group. Moreover, the CdII complex exists as neutral discrete molecule and was found to show tetrahedral geometry.
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