Year-end Sale % OFF 
Abstract
The reaction of Ph2P(O)(OSiMe3) with [(η5-C5H5)TiCl3] or [(η5-C5Me5)TaCl4] in dichloromethane yields the complexes [{(η5-C5H5)TiCl2(µ-Ph2PO2)}2] (1) or [{(η5-C5Me5)TaCl3(µ-Ph2PO2)}2] (2), respectively. Structural analysis of 1 and 2 by single-crystal X-ray diffraction revealed the presence of eight-membered metallacycles consisting of bridgingbidentate diphenylphosphinate groups between two metal centers.Key words: inorganic rings, phosphinate complexes, tantalum, titanium.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
