Abstract
Abstract The octanuclear bismuth(III) thiosalicylate complex, [Bi8(tsal)12(DMF)6](DMF)6 (H2tsal = thiosalicylic acid, DMF = N,N′-dimethylformamide), has been prepared and structurally characterized. The single crystal X-ray structure analysis has demonstrated that the eight Bi atoms form a disk-like cluster core and that each lone pair of two Bi atoms as the asymmetric unit is stereochemically activated.
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