Abstract

A novel one-dimensional coordination polymer, {[Cu(dien)(dimb)](ClO 4) 2} n [dien=diethylenetriamine; dimb=1,3-bis(imidazol-1-ylmethyl)-5-methylbenzene] was synthesized by treatment of [Cu(dien)(im)](ClO 4) 2 (im=imidazole) with the dimb ligand. The complex was characterized by X-ray crystallography and electrospray mass spectrometry. The coordination geometry around Cu(II) is distorted square-based pyramid with N 5 donor set.

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