Abstract
The work in this report presents the synthesis, structural and spectroscopic characterization of a hemiacetal and aldehyde bound diiron(III) complex 1 with two different coordination numbers supported by a tetradentate N2O2 donor H2L ligand, despite the fact that no aldehyde molecules have been added to the solution. The complex 1 is a phenoxo and alkoxo bridged complex and it was generated when oxo-transfer reagent iodosylbenzene was treated to a methanolic solution containing Fe(BF4)2·6H2O and deprotonated H2L ligand. The Fe⋯Fe separation of this complex is 3.158Å.
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