Abstract

The new phenyl/scorpionate hybrid ligand [Ph(pz)BC 5H 10] − has been synthesised and structurally characterised as K + and Tl + salt. The ligand is specifically designed to create half-sandwich complexes in which the metal ion is chelated by the π-electron system of the phenyl ring and by the electron lone pair of the pyrazolyl nitrogen atom. This structural motif is established both by K[Ph(pz)BC 5H 10] and by Tl[Ph(pz)BC 5H 10].

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