Abstract

Stereochemical assignments of a series of substituted cis- and trans-1-trifluoromethyl-2-phenylcyclo-propanes (unsubstituted, bromide, carbonitrile, and carboxamide) based on a detailed analysis of the n.m.r. spectra and on the ten-fold difference in rates in the reaction of cis- and trans-1-trifluoromethyl-2-phenylcyclopropyl carbonitrile with basic hydrogen peroxide are presented.

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