Abstract
Zinc sulfide nanoparticles were synthesized in pores of a perfluorosulfonic membrane by ion exchange fixation of Zn2+ cations followed by the processing with gaseous hydrogen sulfide. Resulting ZnS particles are X-ray amorphous, have a low density, and are clearly expressed in absorption and luminescence spectra. Features of the nanoparticles optical properties were considered in light of electrons photoexcitation on antibonding orbitals (Zn–S)*.
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